Processing of polymer‐derived, aerogel‐filled, SiC foams for high‐temperature insulation
نویسندگان
چکیده
Porous polymer-derived ceramics (PDCs) are outperforming materials when low-density and thermal inertia required. In this frame, insulating foams such as silicon carbide (SiC) ones possess intriguing requisites for aerospace applications, but their conductivity is affected by gas phase heat transfer and, in the high temperature region, radiative mechanisms. Owing to versatility of PDC route, we present a synthesis pathway embed SiC aerogels within open cells foam, thus sensibly decreasing at 1000°C from 0.371 W·m−1K−1 0.243 W·m−1K−1. way, it was possible couple mechanical properties foam with ability aerogels. The presented optimized selecting, among acetone, n-hexane, cyclohexane, proper solvent gelation step aerogel formation obtain mesoporous colloidal structure that, after ceramization 1000°C, presents specific surface area 193 m2·g−1. so-obtained ceramic composites lowest density 0.18 g·cm−3, porosity 90% compressive strength 0.76 MPa.
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ژورنال
عنوان ژورنال: Journal of the American Ceramic Society
سال: 2023
ISSN: ['0002-7820', '1551-2916']
DOI: https://doi.org/10.1111/jace.19118